Support-induced modifications on the CO2 hydrogenation performance of Ni/CeO2: the effect of ZnO doping on CeO2 nanorodsSupport-induced modifications on the CO2 hydrogenation performance of Ni/CeO2: the effect of ZnO doping on CeO2 nanorods Peer-Reviewed Journal Publication Δημοσίευση σε Περιοδικό με Κριτές 2024-01-152022enThe production of either CO or CH4 via the hydrogenation of CO2 is amongst the most promising routes for CO2 utilization. However, kinetic barriers necessitate the use of a catalyst, with Ni/CeO2 being one of the most investigated systems. Nevertheless, surface chemistry fine-tuning via appropriate promotional routes can induce significant modifications on the solid-state properties of catalysts and in turn on their activity/selectivity. In the present work, we originally report on the outstanding selectivity alteration of Ni/CeO2 by ZnO doping. Specifically, Ni-based catalysts supported on ZnO, CeO2 nanorods or a mixed ZnO-CeO2 oxide were synthesized by a modified hydrothermal method and characterized by various physicochemical methods. Notable changes in the reaction pathway were demonstrated, as the presence of ZnO largely favored CO production at T < 450 oC for both Ni/ZnO and Ni/ZnO-CeO2, whereas Ni/CeO2 was completely selective to CH4. These findings were interpreted on the basis of ZnO-induced inhibitory effects on key activity/selectivity descriptors like the redox and basic properties, as well as on the adsorption affinity of CO species, which are considered as intermediate species for CO2 methanation.This research has been co-financed by the European Union and Greek national funds through the Greece 2.0 National Recovery and Resilience Fund, under the call RESEARCH - CREATE - INNOVATE (project code: T2EDK-01378).http://creativecommons.org/licenses/by/4.0/Journal of Co2 Utilization61 Varvoutis Georgios Karakoulia Stamatia A. Lykaki Maria Λυκακη Μαρια Stefa Sofia Στεφα Σοφια Binas Vassilios Marnellos, George, 19..- Konsolakis Michail Κονσολακης Μιχαηλ Elsevier CO2 hydrogenation Ni/CeO2 ZnO promotion Selectivity modification Support effect