A synthetic and crystal structure study of a collection of coordination polymers based on alkaline aroylhydrazonatesA synthetic and crystal structure study of a collection of coordination polymers based on alkaline aroylhydrazonates Peer-Reviewed Journal Publication Δημοσίευση σε Περιοδικό με Κριτές 2015-12-032015enThe reactions of two aroylhydrazone ligands H2LS and H2LAc with alkaline Li(I), Na(I), K(I) and Ba(II) metal ions afforded nine new coordination polymers with different dimensionalities. These illustrate the ionic radii, the ligand substitution and the solvent influence on the formation of the final product. Interestingly, one of them shows porous structure with a 40% unoccupied volume. http://creativecommons.org/licenses/by/4.0/Polyhedron100359-372 David Specklin Samir Mameri Edward Loukopoulos Kostakis Georgios Κωστακης Γεωργιος Richard Welter Elsevier Ligand design Crystal structure Coordination polymers MOFs Alkali metals