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Assessment of tetrabromobisphenol-A (TBBPA) content in plastic waste recovered from WEEE

Kousaiti Athanasia, Chachladakis Ioannis, Savvilotidou Vasiliki, Pivnenko, Kostyantyn, Tyrovola Konstantina, Xekoukoulotakis Nikos, Astrup Thomas Fruergaard, Gidarakos Evaggelos

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URIhttp://purl.tuc.gr/dl/dias/75176964-4489-4496-9959-76344A8DBD2D-
Identifierhttps://doi.org/10.1016/j.jhazmat.2019.121641-
Identifierhttps://www.sciencedirect.com/science/article/pii/S030438941931595X-
Languageen-
Extent11 pagesen
TitleAssessment of tetrabromobisphenol-A (TBBPA) content in plastic waste recovered from WEEEen
CreatorKousaiti Athanasiaen
CreatorΚουσαϊτη Αθανασιαel
CreatorChachladakis Ioannisen
CreatorΧαχλαδακης Ιωαννηςel
CreatorSavvilotidou Vasilikien
CreatorΣαββιλωτιδου Βασιλικηel
CreatorPivnenko, Kostyantynen
CreatorTyrovola Konstantinaen
CreatorΤυροβολα Κωνσταντιναel
CreatorXekoukoulotakis Nikosen
CreatorΞεκουκουλωτακης Νικοςel
CreatorAstrup Thomas Fruergaarden
CreatorGidarakos Evaggelosen
CreatorΓιδαρακος Ευαγγελοςel
PublisherElsevieren
Content SummaryDue to the variability of additives and polymer types used in electrical and electronic equipment (EEE), and in accordance with the European Directive 2012/19/EU, an implementation of sound management practices is necessary. This work focuses on assessing the content of tetrabromobisphenol-A (TBBPA) in acrylonitrile-butadiene-styrene (ABS), polypropylene (PP), polycarbonate (PC) and their polymer blends (i.e. PC/ABS). A total of 36 plastic housing samples originating from microwave ovens, electric irons, vacuum cleaners and DVD/CD players were subjected to microwave-assisted-extraction (MAE) and/or ultrasound-assisted-extraction (UAE). Maximum mean concentration values of TBBPA measured in DVD/CD players and vacuum cleaners ranged between 754−1146 μg/kg, and varied per polymer type, as follows: 510−2515 μg/kg in ABS and 55−3109 μg/kg in PP. The results indicated that MAE was more sufficient than UAE in the extraction of TBBPA from ABS. To optimize the UAE procedure, various solvents were tested. Higher amounts of TBBPA were obtained from ABS and PP using a binary mixture of a polar-non-polar solvent, isopropanol:n-hexane (1:1), whereas the sole use of isopropanol exhibited incomplete extraction.en
Type of ItemPeer-Reviewed Journal Publicationen
Type of ItemΔημοσίευση σε Περιοδικό με Κριτέςel
Licensehttp://creativecommons.org/licenses/by/4.0/en
Date of Item2020-10-29-
Date of Publication2020-
SubjectAcrylonitrile-butadiene-styrene (ABS)en
SubjectMicrowave-assisted-extraction (MAE)en
SubjectPlastic wasteen
SubjectTetrabromobisphenol-A (TBBPA)en
SubjectWEEEen
Bibliographic CitationA. Kousaiti, J.N. Hahladakis, V. Savvilotidou, K. Pivnenko, K. Tyrovola, N. Xekoukoulotakis, T.F. Astrup and E. Gidarakos, "Assessment of tetrabromobisphenol-A (TBBPA) content in plastic waste recovered from WEEE," J. Hazard. Mater., vol. 390, May 2020. doi: 10.1016/j.jhazmat.2019.121641en

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