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Ιδρυματικό Αποθετήριο [SANDBOX]
Πολυτεχνείο Κρήτης
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| URI | http://purl.tuc.gr/dl/dias/3DEBCBCD-207B-4BCB-B0B5-F7099D9B88F5 | - |
| Αναγνωριστικό | https://doi.org/10.1016/j.apsusc.2019.143846 | - |
| Αναγνωριστικό | https://www.sciencedirect.com/science/article/pii/S0169433219326625 | - |
| Γλώσσα | en | - |
| Μέγεθος | 14 pages | en |
| Τίτλος | Cu2O-CuO@biochar composite: synthesis, characterization and its efficient photocatalytic performance | en |
| Δημιουργός | Khataee, Alireza | en |
| Δημιουργός | Kalderis Dimitrios | en |
| Δημιουργός | Καλδερης Δημητριος | el |
| Δημιουργός | Gholami Peyman | en |
| Δημιουργός | Fazli Arezoo | en |
| Δημιουργός | Moschogiannaki Marilena | en |
| Δημιουργός | Binas Vasileios | en |
| Δημιουργός | Lykaki Maria | en |
| Δημιουργός | Λυκακη Μαρια | el |
| Δημιουργός | Konsolakis Michail | en |
| Δημιουργός | Κονσολακης Μιχαηλ | el |
| Εκδότης | Elsevier | en |
| Περίληψη | This research focuses on the facile hydrothermal preparation of Cu2O-CuO@biochar (Cu2O-CuO@BC) compo-sites of different BC content (0.5, 1.0, and 2.0 g/L) as efficient photocatalysts for the decomposition and mi-neralization of Reactive Orange 29 (RO29). The textural and morphological properties of biochar-based com-posites were studied utilizing BET, TEM, and SEM analyses. Moreover, EDX, XRD, UV–Vis, DRS and FTIRcharacterization was carried out to evaluate the elemental composition, crystalline structure, optical char-acteristics and functional groups of the samples, respectively. The Cu2O-CuO@BC-1.0 composite with a BCcontent of 1.0 g/L exhibited superior photocatalytic performance than the individual counterparts BC and Cu2O-CuO, due to its narrow band gap and high surface area. These characteristics led to the synergetic ability of UVirradiation and photocatalytic performance of Cu2O-CuO@BC to generate oxidizing species and subsequentradical reactions. The generation of some by-products was verified using GC–MS analysis and accordingly, apossible pathway was proposed. 94.12% degradation efficiency of RO29 was obtained by Cu2O-CuO@BC-1.0composite at the natural pH of RO29 solution (8.9) and initial RO29 concentration of 20 mg/L after 90 min ofphotocatalysis. Under identical conditions, 47.31% and 79.62% COD removal efficiencies were observed after 90and 180 min treatment, respectively. | en |
| Τύπος | Peer-Reviewed Journal Publication | en |
| Τύπος | Δημοσίευση σε Περιοδικό με Κριτές | el |
| Άδεια Χρήσης | http://creativecommons.org/licenses/by/4.0/ | en |
| Ημερομηνία | 2020-03-31 | - |
| Ημερομηνία Δημοσίευσης | 2019 | - |
| Θεματική Κατηγορία | Copper oxide composite | en |
| Θεματική Κατηγορία | Photocatalyst | en |
| Θεματική Κατηγορία | Hydrothermal synthesis | en |
| Θεματική Κατηγορία | Advanced water treatment | en |
| Θεματική Κατηγορία | Biochar | en |
| Βιβλιογραφική Αναφορά | A. Khataee, D. Kalderis, P. Gholami, A. Fazli, M. Moschogiannaki, V. Binas, M. Lykaki and M. Konsolakis, "Cu2O-CuO@biochar composite: Synthesis, characterization and its efficient photocatalytic performance," Appl. Surf. Sci., vol. 498, Dec. 2019. doi: 10.1016/j.apsusc.2019.143846 | en |
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