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The supramolecular architecture of the second coordination sphere complex between the ammonia adduct of tris(pentafluorophenyl)borane and pyrimidine: two interpenetrating chiral (10,3)-a (srs) nets assembled through hydrogen bonding

Annie K. Powell, Kostakis Georgios, Simon J. Lancaster, David L. Hughes, Anna-Marie Fuller

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URI: http://purl.tuc.gr/dl/dias/4FB0DB26-0060-4CAD-B2B0-1D9CEBAEEE7D
Έτος 2011
Τύπος Δημοσίευση σε Περιοδικό με Κριτές
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Βιβλιογραφική Αναφορά A.-M. Fuller, D. L. Hughes, G. E. Kostakis, S. J. Lancaster, and A. K. Powell, "The supramolecular architecture of the second coordination sphere complex between the ammonia adduct of tris(pentafluorophenyl)borane and pyrimidine: two interpenetrating chiral (10,3)-a (srs) nets assembled through hydrogen bonding", Inorganica Chim. Acta, vol. 366, no. 1, pp. 380-383, Jan. 2011. doi:10.1016/j.ica.2010.10.022
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Περίληψη

Treatment of the ammonia adduct of tris(pentafluorophenyl)borane with 1.5 equivalents of pyrimidine affords a crystalline supramolecular complex. The solid state structure of the chloroform solvate has been determined by X-ray crystallography and is composed of two interpenetrating chiral (10,3)-a (srs) nets assembled through N–H⋯N hydrogen bonding interactions.

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