Synthesis, structural and theoretical studies of a rare hexameric water cluster held in the lattice of {[Zn(HL)(phen)(H2O)]∙3(H2O)}2 (H3L = trans-aconitic acid)
Kostakis Georgios, Ebbe Nordlander, Athanassios C. Tsipis, Matti Haukka, Plakatouras, John C
Το έργο με τίτλο Synthesis, structural and theoretical studies of a rare hexameric water cluster held in the lattice of {[Zn(HL)(phen)(H2O)]∙3(H2O)}2 (H3L = trans-aconitic acid) από τον/τους δημιουργό/ούς Kostakis Georgios, Ebbe Nordlander, Athanassios C. Tsipis, Matti Haukka, Plakatouras, John C διατίθεται με την άδεια Creative Commons Αναφορά Δημιουργού 4.0 Διεθνές
Βιβλιογραφική Αναφορά
G. E. Kostakis, E. Nordlander, A. C. Tsipis, M. Haukka, and J. C. Plakatouras, "Synthesis, structural and theoretical studies of a rare hexameric water cluster held in the lattice of {[Zn(HL)(phen)(H2O)]∙3(H2O)}2 (H3L = trans-aconitic acid)", Inorganic Chem. Communicat., vol. 14, no. 1, pp. 87-91, Jan. 2011. doi:10.1016/j.inoche.2010.09.038
https://doi.org/10.1016/j.inoche.2010.09.038
The reaction of Zn(NO3)2∙3(H2O) with trans-aconitic acid (H3L), in presence of chelating 1,10-phenanthroline, leads to the formation of a dinuclear unit {[Zn(HL)(phen)(H2O)]∙3(H2O)}2. The lattice water molecules are assembled as a centrosymmetric hexamer. The crystal structure, thermal studies, theoretical calculations, and the factors that stabilize this water hexamer are presented.