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A comparative treatment of stabilized landfill leachate: coagulation/activated carbon adsorption vs. electrochemical treatment

Papastavrou Chrystalla, Mantzavinos Dionysis, Diamantopoulos Evaggelos

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URI: http://purl.tuc.gr/dl/dias/129BCAA4-4AE0-442B-8D64-7DBECA5B4B5B
Year 2009
Type of Item Peer-Reviewed Journal Publication
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Bibliographic Citation C. Papastavrou, D. Mantzavinos and E. Diamadopoulos, "A comparative treatment of stabilized landfill leachate: coagulation and activated carbon adsorption vs. electrochemical oxidation," Environ. Technol., vol. 30, no. 14, pp. 1547-1553, Aug. 2009. doi: 10.1080/09593330903252240 https://doi.org/10.1080/09593330903252240
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Summary

This work investigated the treatment of a landfill leachate that had previously undergone biological treatment. Two treatment schemes were compared: the first one involved coagulation followed by activated carbon adsorption, whilst the second was electrochemical treatment. Coagulation with alum resulted in a 50% removal of chemical oxygen demand (COD). The optimum aluminium dose was 3 mM Al3+. Activated carbon adsorption of stabilized leachate that had been previously treated by coagulation resulted in an overall 80% removal of COD. However, a significant part of the organic matter (corresponding to 170 mg/L) was non-adsorbable. Electrochemical oxidation over a boron-doped diamond electrode led to about 90% COD removal in 240 min with the resulting stream having a COD content as low as 50 mg/L. An increase in current intensity from 15 A to 21 A had no practical effect on the overall COD removal, which followed first-order kinetics.

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