Ιδρυματικό Αποθετήριο [SANDBOX]
Πολυτεχνείο Κρήτης
EN  |  EL

Αναζήτηση

Πλοήγηση

Ο Χώρος μου

Mechanistic studies on hydrodeoxygenation of furfural to 2-Methyl furan via ring C-H bond activations

Panagiotopoulou Paraskevi, Vlachos G. Dionisios, Gilkey Matthew, Bingjun Xu

Απλή Εγγραφή

URIhttp://purl.tuc.gr/dl/dias/EB273EF8-2702-4F41-A787-42D57F663EA7-
Αναγνωριστικόhttps://aiche.confex.com/aiche/2014/webprogram/Paper364854.html-
Γλώσσαen-
ΤίτλοςMechanistic studies on hydrodeoxygenation of furfural to 2-Methyl furan via ring C-H bond activationsen
ΔημιουργόςPanagiotopoulou Paraskevien
ΔημιουργόςΠαναγιωτοπουλου Παρασκευηel
ΔημιουργόςVlachos G. Dionisiosen
ΔημιουργόςGilkey Matthewen
ΔημιουργόςBingjun Xuen
ΠερίληψηRemoval of excess oxygen-containing functional groups in furanic compounds, e.g. furfural and 5-hydroxymethylfurfural to 2-methyl furan and dimethylfuran, is a key step in the upgrade of cellulosic and hemicellulosic biomass-derived molecules. Mildly oxidized Ru/C catalyst shows remarkable activity and selectivity towards the hydrodeoxygenation reactions; however, molecular level understanding on the catalyst surface-mediated chemical transformation is still lacking. We show that both metal-mediated hydrogenation and Lewis acid-mediated MPV reaction are responsible for hydrogenating C=O to C-OH. In addition, isotopic labeling experiments with detailed mass fragmentation analysis demonstate that ring C-H bond activations are necessary for the C-OH bond scission. en
ΤύποςΣύντομη Δημοσίευση σε Συνέδριοel
ΤύποςConference Short Paperen
Άδεια Χρήσηςhttp://creativecommons.org/licenses/by/4.0/en
Ημερομηνία2015-11-15-
Ημερομηνία Δημοσίευσης2014-
Βιβλιογραφική ΑναφοράB. Xu, D.G. Vlachos, P. Panagiotopoulou, M. Gilkey. (2014, Nov.). Mechanistic studies on hydrodeoxygenation of furfural to 2-Methyl furan via ring C-H bond activations. Pressented at 14AIChE Annual Meeting. [Online]. Available:https://aiche.confex.com/aiche/2014/webprogram/Paper364854.htmlen

Υπηρεσίες

Στατιστικά

 

Copyright © DIAS 2013