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Square-prismatic vs. square-antiprismatic coordination in complexes of lead(II) with a simple bidentate chelating ligand; effects of intermolecular hydrogen bonding

Elefteria Psillakis

Απλή Εγγραφή


URIhttp://purl.tuc.gr/dl/dias/F771EC85-D245-4487-8B4F-E24D15ED6D05-
Αναγνωριστικόhttps://doi.org/ 10.1039/A703643D-
Γλώσσαen-
Μέγεθος2 pagesen
ΤίτλοςSquare-prismatic vs. square-antiprismatic coordination in complexes of lead(II) with a simple bidentate chelating ligand; effects of intermolecular hydrogen bondingen
ΔημιουργόςElefteria Psillakisen
ΔημιουργόςJohnáC Jefferyen
ΕκδότηςRoyal Society of Chemistryen
ΠερίληψηWhereas the eight-coordinate complex cation of [PbL4][(MeO)2PO2]·2H2O [L = 3-(2-pyridyl)pyrazole] has square prismatic geometry stabilised by hydrogen bonding between the pyrazolyl NH groups and the dimethylphosphate anion, the complex cation of [PbL4][PF6]2, in which there are no significant hydrogen-bonding interactions, has a structure distorted towards square antiprismatic with a 22° twist between the planes.en
ΤύποςPeer-Reviewed Journal Publicationen
ΤύποςΔημοσίευση σε Περιοδικό με Κριτέςel
Άδεια Χρήσηςhttp://creativecommons.org/licenses/by/4.0/en
Ημερομηνία2015-09-25-
Ημερομηνία Δημοσίευσης1997-
Βιβλιογραφική ΑναφοράE. Psillakis , J. C. Jeffery ,"Square-prismatic vs. square-antiprismatic coordination in complexes of lead(II) with a simple bidentate chelating ligand; effects of intermolecular hydrogen bonding ",Chem. Commun., vol.20 ,pp. 1965-1966,1997.doi: 10.1039/A703643Den

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