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Institutional Repository [SANDBOX]
Technical University of Crete
Technical University of Crete
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| URI: | http://purl.tuc.gr/dl/dias/F771EC85-D245-4487-8B4F-E24D15ED6D05 | ||
| Year | 1997 | ||
| Type of Item | Peer-Reviewed Journal Publication | ||
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| Bibliographic Citation | E. Psillakis , J. C. Jeffery ,"Square-prismatic vs. square-antiprismatic coordination in complexes of lead(II) with a simple bidentate chelating ligand; effects of intermolecular hydrogen bonding ",Chem. Commun., vol.20 ,pp. 1965-1966,1997.doi: 10.1039/A703643D https://doi.org/ 10.1039/A703643D | ||
| Appears in Collections |
Whereas the eight-coordinate complex cation of [PbL4][(MeO)2PO2]·2H2O [L = 3-(2-pyridyl)pyrazole] has square prismatic geometry stabilised by hydrogen bonding between the pyrazolyl NH groups and the dimethylphosphate anion, the complex cation of [PbL4][PF6]2, in which there are no significant hydrogen-bonding interactions, has a structure distorted towards square antiprismatic with a 22° twist between the planes.
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