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Institutional Repository [SANDBOX]
Technical University of Crete
Technical University of Crete
EN
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EL
| URI | http://purl.tuc.gr/dl/dias/3A4CD4A2-AB91-4C03-BF1C-DA572E3EAD21 | - |
| Identifier | https://doi.org/10.1016/S0277-5387(00)88139-5 | - |
| Identifier | https://www.sciencedirect.com/science/article/pii/S0277538700881395 | - |
| Language | en | - |
| Extent | 10 pages | el |
| Title | A study of crystal packing in a series of closely related square-planar palladium(II) and platinum(II) complexes | en |
| Creator | Psyllaki Eleftheria | en |
| Creator | Ψυλλακη Ελευθερια | el |
| Creator | Bardwell David A. | en |
| Creator | Crossle John G. | en |
| Creator | Orpen, A. Guy | en |
| Creator | Jeffer John C. | en |
| Creator | Tilley Elizabeth E. M. | en |
| Publisher | Pergamon | en |
| Content Summary | The crystal structures of the series of four-coordinate complexes [PdL1Cl) · CH2Cl2 (1·CH2Cl2), [PtL1Cl]·CH2Cl2 (2·CH2Cl2), [PdL3Cl][PF6 · CH2Cl2 (3 · CH2Cl2) and [PdL4Cl][PF6 (4) [HL1 = 6-(2-hydroxyphenyl)-2,2′-bipyridine; L3 = 6-(2-dimethylaminophenyl)-2,2′-bipyridine; L4 = 2-(2-dimethylaminophenyl)-1,10-phenanthroline] are compared and contrasted to examine the extent to which aromatic π-stacking interactions contribute to crystal packing. Complexes 1 and 2 have very similar planar molecular structures but stack in different ways; molecules of 1 form a linear stack in which overlap of the aromatic ligands is maximized between adjacent molecules and there is no PdPd interaction, whereas in 2 there are axial PtPt interactions within the linear stack but less overlap between adjacent aromatic ligands. | en |
| Type of Item | Peer-Reviewed Journal Publication | en |
| Type of Item | Δημοσίευση σε Περιοδικό με Κριτές | el |
| License | http://creativecommons.org/licenses/by/4.0/ | en |
| Date of Item | 2015-09-24 | - |
| Date of Publication | 1994 | - |
| Subject | Crystal packing | en |
| Bibliographic Citation | D. A. Bardwell, J. G. Crossley, J. C. Jeffery, A. G. Orpen, E. Psillakis, E. E. Tilley, M. D Ward, "A study of crystal packing in a series of closely related square-planar palladium(II) and platinum(II) complexes, " Polyhendron, vol. 13, no. 15–16, pp. 2291–2300, Aug. 1994. doi: 10.1016/S0277-5387(00)88139-5 | en |
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