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A study of crystal packing in a series of closely related square-planar palladium(II) and platinum(II) complexes

Psyllaki Eleftheria, Bardwell David A., Crossle John G., Orpen, A. Guy, Jeffer John C., Tilley Elizabeth E. M.

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URIhttp://purl.tuc.gr/dl/dias/3A4CD4A2-AB91-4C03-BF1C-DA572E3EAD21-
Identifierhttps://doi.org/10.1016/S0277-5387(00)88139-5-
Identifierhttps://www.sciencedirect.com/science/article/pii/S0277538700881395-
Languageen-
Extent10 pagesel
TitleA study of crystal packing in a series of closely related square-planar palladium(II) and platinum(II) complexesen
CreatorPsyllaki Eleftheriaen
CreatorΨυλλακη Ελευθεριαel
CreatorBardwell David A.en
CreatorCrossle John G.en
CreatorOrpen, A. Guyen
CreatorJeffer John C.en
CreatorTilley Elizabeth E. M.en
PublisherPergamonen
Content SummaryThe crystal structures of the series of four-coordinate complexes [PdL1Cl) · CH2Cl2 (1·CH2Cl2), [PtL1Cl]·CH2Cl2 (2·CH2Cl2), [PdL3Cl][PF6 · CH2Cl2 (3 · CH2Cl2) and [PdL4Cl][PF6 (4) [HL1 = 6-(2-hydroxyphenyl)-2,2′-bipyridine; L3 = 6-(2-dimethylaminophenyl)-2,2′-bipyridine; L4 = 2-(2-dimethylaminophenyl)-1,10-phenanthroline] are compared and contrasted to examine the extent to which aromatic π-stacking interactions contribute to crystal packing. Complexes 1 and 2 have very similar planar molecular structures but stack in different ways; molecules of 1 form a linear stack in which overlap of the aromatic ligands is maximized between adjacent molecules and there is no PdPd interaction, whereas in 2 there are axial PtPt interactions within the linear stack but less overlap between adjacent aromatic ligands.en
Type of ItemPeer-Reviewed Journal Publicationen
Type of ItemΔημοσίευση σε Περιοδικό με Κριτέςel
Licensehttp://creativecommons.org/licenses/by/4.0/en
Date of Item2015-09-24-
Date of Publication1994-
SubjectCrystal packingen
Bibliographic CitationD. A. Bardwell, J. G. Crossley, J. C. Jeffery, A. G. Orpen, E. Psillakis, E. E. Tilley, M. D Ward, "A study of crystal packing in a series of closely related square-planar palladium(II) and platinum(II) complexes, " Polyhendron, vol. 13, no. 15–16, pp. 2291–2300, Aug. 1994. doi: 10.1016/S0277-5387(00)88139-5en

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