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A dinuclear double-helical complex of potassium ions with acompartmental bridging ligand containing two terdentate N-donorfragments

Elefteria Psillakis, Johná C Jeffery, Joná A McCleverty, Michaelá D Ward

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URI: http://purl.tuc.gr/dl/dias/012693B1-F045-4C4F-87C7-7BE9D10DAD6D
Year 1997
Type of Item Peer-Reviewed Journal Publication
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Bibliographic Citation J. C Jeffery, J. A McCleverty, M. D Ward ,E.Psillakis , "A dinuclear double-helical complex of potassium ions with acompartmental bridging ligand containing two terdentate N-donorfragments " ,Chem. Commun.,vol.5 , pp. 479-480, 1997.doi: 10.1039/A607984I https://doi.org/ 10.1039/A607984I
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Summary

Recently helicates have become a well known structural motif in supramolecular coordination chemistry.1–4 They are of particular interest not just for their appealing structures but also because of the processes of molecular recognition and self- assembly that are required for their formation. Their formation requires (i) ligands which contain several discrete metal-ion binding domains, and (ii) metal ions with specific preferences for particular coordination geometries that match the ligand binding sites.

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