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Institutional Repository [SANDBOX]
Technical University of Crete
Technical University of Crete
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| URI: | http://purl.tuc.gr/dl/dias/A71FF72D-711A-4221-8DEB-819568FAECC6 | ||
| Year | 1997 | ||
| Type of Item | Peer-Reviewed Journal Publication | ||
| License |
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| Bibliographic Citation | J. C Jeffery, P.L Jones, K. LV Mann, E. Psillakis, J. A McCleverty, M. D Ward, C. M White , "Copper(II)-templated assembly of tetranuclear grid-like complexesfrom simple pyridine–pyrazole ligands ",Ch.Communicat.,vol. 2 ,pp.175-176,1997.doi : 10.1039/A606827H https://doi.org/10.1039/A606827H | ||
| Appears in Collections |
Reaction of Cu(O 2 CMe) 2 ·H 2 O with HL 1 [3-(2-pyridyl)pyrazole] or HL 2 [6-(3-pyrazolyl)-2,2′-bipyridine] and NH 4 PF 6 followed by crystallisation of the crude products from dmf–ether affords [Cu 4 L 1 6 (dmf) 2 ][PF 6 ] 2 1 and [Cu 4 L 2 4 (dmf) 4 ]- [PF 6 ] 4 2 respectively, in which the deprotonated pyrazolyl groups act as bridging ligands and the 2 × 2 grid–like architectures are a result of the preference of the Cu II ions for elongated square-pyramidal coordination geometries.
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