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Ιδρυματικό Αποθετήριο [SANDBOX]
Πολυτεχνείο Κρήτης
Πολυτεχνείο Κρήτης
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| URI: | http://purl.tuc.gr/dl/dias/EB9A5CDA-A11A-4E2B-BE9F-3BC0CCFDFAFC | ||
| Έτος | 2008 | ||
| Τύπος | Δημοσίευση σε Περιοδικό με Κριτές | ||
| Άδεια Χρήσης |
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| Βιβλιογραφική Αναφορά | L.Vidal, A.Chisvert, A. Canals, .E Psillakis, A.Lapkin, F. Acosta, K. J Edler, J. A Holdaway, F.Marken , "Chemically surface modified carbon nanoparticle carrier for phenolic pollutants: Extraction and electrochemical determination of benzophenone-3 and triclosan ",Anal. Chimi. Acta ,vol.616, no.1 ,pp.28–35,2008.doi:10.1016/j.aca.2008.04.011 https://doi.org/10.1016/j.aca.2008.04.011 | ||
| Εμφανίζεται στις Συλλογές |
Chemically surface-modified (tosyl-functionalized) carbon nanoparticles (Emperor 2000 from Cabot Corp.) are employed for the extraction and electrochemical determination of phenolic impurities such as benzophenone-3 (2-hydroxy-4-methoxybenzophenone) or triclosan (5-chloro-2-(2,4-dichlorophenoxy)phenol). The hydrophilic carbon nanoparticles are readily suspended and separated by centrifugation prior to deposition onto suitable electrode surfaces and voltammetric analysis. Voltammetric peaks provide concentration information over a 10–100M range and an estimated limit of detection of ca. 10M (or 2.3 ppm) for benzophenone-3 and ca. 20 M (or 5.8 ppm) for triclosan.Alternatively, analyte-free carbon nanoparticles immobilized at a graphite or glassy car- bon electrode surface and directly immersed in analyte solution bind benzophenone-3 and triclosan (both with an estimated Langmuirian binding constants of K ≈ 6000 mol−1 dm3 at pH 9.5) and they also give characteristic voltammetric responses (anodic for triclosan and cathodic for benzophenone-3) with a linear range of ca. 1–120 M. The estimated limit of detection is improved to ca.5 M (or 1.2 ppm) for benzophenone-3 and ca. 10 M (or 2.3 ppm) for triclosan. Surface functionalization is discussed as the key to further improvements in extraction and detection efficiency.
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