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Complexes of a new bidentate chelating pyridyl/sulfonamide ligand with copper(II), cobalt(II) and palladium(II): crystal structures and spectroscopic properties

Elefteria Psillakis, Carl A Otter, Samantha M Couchman, John C Jeffery, Karen LV Mann, Michael D Ward

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URIhttp://purl.tuc.gr/dl/dias/E9BDD35A-9831-42EE-A8AF-C163C729E75F-
Identifierhttps://doi.org/10.1016/S0020-1693(98)00018-8-
Languageen-
TitleComplexes of a new bidentate chelating pyridyl/sulfonamide ligand with copper(II), cobalt(II) and palladium(II): crystal structures and spectroscopic propertiesen
CreatorElefteria Psillakisen
CreatorCarl A Otteren
Creator Samantha M Couchmanen
CreatorJohn C Jefferyen
Creator Karen LV Mannen
CreatorMichael D Warden
PublisherElsevieren
Content SummaryReaction of the bidentate ligand 2-(2-aminophenyl)pyridine with p-toluenesulfonyl chloride afforded the new bidentate ligand HL which contains potentially chelating pyridyl and (protonated) sulfonamide N-donor binding sites. The crystal structure of the ligand shows that the sulfonamide NH proton is involved in a hydrogen-bonding interaction with the pyridyl N atom, resulting in a near-coplanar arrangement of the pyridyl and phenyl rings.en
Type of ItemPeer-Reviewed Journal Publicationen
Type of ItemΔημοσίευση σε Περιοδικό με Κριτέςel
Licensehttp://creativecommons.org/licenses/by/4.0/en
Date of Item2015-09-24-
Date of Publication1998-
Bibliographic CitationC. A Otter, S. M Couchman, J. C Jeffery, K. LV Mann, E. Psillakis, M.D Ward , "Complexes of a new bidentate chelating pyridyl/sulfonamide ligand with copper(II), cobalt(II) and palladium(II): crystal structures and spectroscopic properties ", Inor.a chimica acta , vol. 278, no. 2, pp. 178–184 ,1998.doi:10.1016/S0020-1693(98)00018-8en

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