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Institutional Repository [SANDBOX]
Technical University of Crete
Technical University of Crete
EN
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EL
| URI | http://purl.tuc.gr/dl/dias/68A2E9EF-EC14-478A-B146-E9F14834CDD3 | - |
| Identifier | https://doi.org/10.1016/S0021-9673(03)00390-X | - |
| Identifier | https://www.sciencedirect.com/science/article/pii/S002196730300390X?via%3Dihub | - |
| Language | en | - |
| Extent | 9 pages | en |
| Title | Hollow-fibre liquid-phase microextraction of phthalate esters from water | en |
| Creator | Kalogerakis Nikos | en |
| Creator | Καλογερακης Νικος | el |
| Creator | Psyllaki Eleftheria | en |
| Creator | Ψυλλακη Ελευθερια | el |
| Publisher | Elsevier | en |
| Content Summary | A simple and efficient liquid-phase microextraction (LPME) technique using a hollow-fibre membrane, in conjunction with gas chromatography–mass spectrometry has been developed for the extraction and analysis of six phthalate esters in water samples. Parameters such as extraction solvent, agitation of the sample, salt addition and extraction time were controlled and optimised. The developed protocol was found to yield a linear calibration curve in the concentration range 21 21 from 0.02 to 10 mg l for most target analytes and the limits of detection were in the low mg l level, ranging between 21 0.005 and 0.1 mg l . The repeatability of the method varied between 4% and 11%. Under the present experimental conditions, the performance of the method was found comparable to that of solid-phase microextraction (SPME). The advantage of the proposed method over SPME was that it eliminated carry-over of analytes between runs. The applicability of the developed hollow-fibre LPME method and SPME was demonstrated for real water samples. The ability of both microextraction methods to concentrate many organic analytes was demonstrated as both methods allowed the confirmation of the presence of an extra contaminant (ethyl p-ethoxybenzoate) in bottled mineral water samples. | en |
| Type of Item | Peer-Reviewed Journal Publication | en |
| Type of Item | Δημοσίευση σε Περιοδικό με Κριτές | el |
| License | http://creativecommons.org/licenses/by/4.0/ | en |
| Date of Item | 2015-09-23 | - |
| Date of Publication | 2003 | - |
| Subject | Hollow-fibre membranes | en |
| Subject | Liquid-phase microextraction | en |
| Subject | Extraction methods | en |
| Subject | Water analysis | en |
| Subject | Phthalates | en |
| Subject | Ethyl ethoxybenzoate | en |
| Bibliographic Citation | E. Psillakis and N. Kalogerakis , "Hollow-fibre liquid-phase microextraction of phthalate esters from water, " J. Chromatogr. A, vol. 999, no.1-2, pp.145–153, May 2003. doi: 10.1016/S0021-9673(03)00390-X | en |
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