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Anion-templated assembly of a supramolecular cage complex

Elefteria Psillakis, Michael D Ward, Jon A McCleverty, John C Jeffery, Charles‐Antoine Carraz, Karen LV Mann, James S Fleming

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URIhttp://purl.tuc.gr/dl/dias/EF6B6050-2017-4952-B1CA-B6A1D3D97B8C-
Identifierhttps://doi.org/10.1002/(SICI)1521-3773(19980518)37:9<1279::AID-ANIE1279>3.0.CO;2-Q-
Languageen-
TitleAnion-templated assembly of a supramolecular cage complexen
CreatorElefteria Psillakisen
CreatorMichael D Warden
CreatorJon A McClevertyen
CreatorJohn C Jefferyen
CreatorCharles‐Antoine Carrazen
CreatorKaren LV Mannen
CreatorJames S Flemingen
PublisherWiley‐vch verlag gmbhen
Content SummaryTHe templating effect of the tetrafluoroborate ion leads to assembly of four CoII ions and six bridging ligands around this anion to give a tetrahedral complex with a bridging ligand along each edge and the anion trapped in the central cavity (shown below). Surprisingly under identical conditions but with NiII a simpler dinuclear complex forms. en
Type of ItemPeer-Reviewed Journal Publicationen
Type of ItemΔημοσίευση σε Περιοδικό με Κριτέςel
Licensehttp://creativecommons.org/licenses/by/4.0/en
Date of Item2015-09-23-
Date of Publication1998-
Bibliographic CitationJ. S Fleming, K. LV Mann, C.A.Carraz, E.Psillakis, J. C Jeffery, J. A McCleverty, M.D Ward , "Anion-Templated Assembly of a Supramolecular Cage Complex ",Ang. chem. interna. edit.,vol.37,no.9 ,pp.1279-1281,1998.doi:10.1002/(SICI)1521-3773(19980518)37:9<1279::AID-ANIE1279>3.0.CO;2-Qen

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