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Anion-templated assembly of a supramolecular cage complex

Elefteria Psillakis, Michael D Ward, Jon A McCleverty, John C Jeffery, Charles‐Antoine Carraz, Karen LV Mann, James S Fleming

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URI: http://purl.tuc.gr/dl/dias/EF6B6050-2017-4952-B1CA-B6A1D3D97B8C
Year 1998
Type of Item Peer-Reviewed Journal Publication
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Bibliographic Citation J. S Fleming, K. LV Mann, C.A.Carraz, E.Psillakis, J. C Jeffery, J. A McCleverty, M.D Ward , "Anion-Templated Assembly of a Supramolecular Cage Complex ",Ang. chem. interna. edit.,vol.37,no.9 ,pp.1279-1281,1998.doi:10.1002/(SICI)1521-3773(19980518)37:9<1279::AID-ANIE1279>3.0.CO;2-Q https://doi.org/10.1002/(SICI)1521-3773(19980518)37:9<1279::AID-ANIE1279>3.0.CO;2-Q
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Summary

THe templating effect of the tetrafluoroborate ion leads to assembly of four CoII ions and six bridging ligands around this anion to give a tetrahedral complex with a bridging ligand along each edge and the anion trapped in the central cavity (shown below). Surprisingly under identical conditions but with NiII a simpler dinuclear complex forms.

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