Institutional Repository [SANDBOX]
Technical University of Crete
EN  |  EL

Search

Browse

My Space

Anion-templated assembly of a supramolecular cage complex

Elefteria Psillakis, Michael D Ward, Jon A McCleverty, John C Jeffery, Charles‐Antoine Carraz, Karen LV Mann, James S Fleming

Full record

URI: http://purl.tuc.gr/dl/dias/EF6B6050-2017-4952-B1CA-B6A1D3D97B8C
Year 1998
Type of Item Peer-Reviewed Journal Publication
License
Details
Bibliographic Citation J. S Fleming, K. LV Mann, C.A.Carraz, E.Psillakis, J. C Jeffery, J. A McCleverty, M.D Ward , "Anion-Templated Assembly of a Supramolecular Cage Complex ",Ang. chem. interna. edit.,vol.37,no.9 ,pp.1279-1281,1998.doi:10.1002/(SICI)1521-3773(19980518)37:9<1279::AID-ANIE1279>3.0.CO;2-Q https://doi.org/10.1002/(SICI)1521-3773(19980518)37:9<1279::AID-ANIE1279>3.0.CO;2-Q
Appears in Collections
Journal Publications in Community School of Chemical and Environmental Engineering

Summary

THe templating effect of the tetrafluoroborate ion leads to assembly of four CoII ions and six bridging ligands around this anion to give a tetrahedral complex with a bridging ligand along each edge and the anion trapped in the central cavity (shown below). Surprisingly under identical conditions but with NiII a simpler dinuclear complex forms.

Services

Statistics

 

Copyright © DIAS 2013